James Bond (Pierce Brosnan) wears a pair of Church's Chetwynd shoes in the movie GoldenEye (1995). These Walnut brown full brogue shoes in Nevada leather are worn in the Monaco scenes with the blue wool double breasted Brioni Plinio blazer and woolen sporty sand colour Brioni Snello trousers.
A pair of Church's Chetwynd worn by Pierce Brosnan in GoldenEye was auctioned on 19 December 2007 at the Christie's Film & Entertainment Memorabilia auction in London, South Kensington and sold for £1080.
The Chetwynd model is still available at Church's for £410. The current model is slightly different, for example the old model has six pairs of eyelets (holes for the laces) and the current model has five pairs of eyelets. On eBay you can always find a good selection of Chetwynd shoes.
The Chetwynd is not the only shoe model worn in the movie. Bond also wears black Church's Diplomat brogues.
George Lazenby wears very similar brown brogues in the movie On Her Majesty's Secret Service (1967) together with grey pants, white checked shirt and sand color cardigan, but the brand of those shoes is unknown.