Vesper (Eva Green) wears Versace 4061 sunglasses in the James Bond film Casino Royale, when Bond types his resignation on the Vaio Laptop, and she steers the Spirit 54 yacht into Venice. The sunglasses are Smoke Olive with Lite Olive Fade lenses, color code 514/16. The Plastic Frame measures 68-17-115 (eye/bridge/temple). The glasses already rarely available when the movie came out, but might be near to impossible to find now.
Thanks to Kittlemeier for the alert